Iranian Journal of Materials Science and Engineering

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C-SiC composites with carbon-based mesocarbon microbeads (MCMB) preforms are new type of highpreformance and high-temperature structural materials for aerospace applications. In this study MCMB-SiC composites with high density (2.41 g.cm-3) and high bending strength (210 MPa,) was prepared by cold isostatic press of mixed mesophase carbon powder derived from mesophase pitch with different amount (0, 2.5, 5%) nano SiC particles. All samples were carbonized under graphite bed until 1000 °C and finally liquid silicon infiltration (LSI). Microstructure observations resultant samples were performed by scanning electron microscopy and transition electron microscopy (SEM & TEM). Density, porosity and bending strength of final samples were also measured and calculated. Results indicates that the density of samples with nano additive increased significantly in compare to the free nano additives samples.

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In this research, infiltration behavior of W-Ag composite compacts with Nickel and Cobalt as additives has been investigated. Nickel and Cobalt were added to Tungsten powder by two distinct methods: mixing elementally and reduction of salt solution. The coated Tungsten powders were compacted under controlled pressures to make porous skeleton with 32-37 vol. % porosity. Infiltration process was carried out at 1100 ̊C under a reducing atmosphere for 1h. The effect of additives on infiltration of Ag and density were evaluated by SEM and Archimedes methods. Properties of the specimens were compared following two distinct processes namely: I) sintering simultaneously with infiltration process and II) sintering prior to infiltration (pre-sintering process). It was found that specimens which were pre-sintered and then infiltrated with molten silver represent higher hardness and finer microstructure than the specimens infiltrated simultaneously with sintering.

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In order to further enhance the Ni/Ce 0.8Gd0.2O2-δ (Ni/GDC20) cermet anodic performance for low temperature solid oxide fuel cell (LT-SOFC), a study was conducted on the nanostructuring of NiO/GDC composite by only once wet-infiltration of rhodium chloride precursor. By using electrochemical impedance spectroscopy (EIS) analysis, the effect of only one drop of Rh-infiltrating solution on the anodic polarization resistance was examined using symmetric Ni–GDC20|GDC20|Pt electrolyte-supported cell at 400-600 °C. Nanostructural evolution before and after H 2 reduction at 600 °C and also after anodic performance test was investigated by atomic force microscopy (AFM), field emission scanning electron microscopy (FE-SEM), and transmission electron microscopy (TEM) techniques in comparison to the anode itself. Despite the fine distribution of Rh-infiltrated nanoparticles having average particle size of 11.7 nm, the results showed ineffectiveness and inability of the Rh nanoparticles to succeed in decreasing of anodic polarization resistance for H 2 oxidation reaction in LT-SOFC.

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In this paper the feasibility of fabricating controlled porous skeleton of pure tungsten at low temperature by addition of submicron particles to tungsten powder (surface activated sintering) has been studied and the best parameters for subsequent infiltration of Cu were acquired. The effects of addition of submicron particles and sintering temperature on porous as well as infiltrated samples were studied. The samples were examined by scanning electron microscopy (SEM), Vickers hardness measurements and tensile test. The composites made have been investigated and revealed the making W-Cu composite with good density, penetrability, hardness and microstructure. Consequently, the sintering temperature was reduced considerably (Ts≤1650^oC) and a homogeneous porous tungsten was obtained. Also, composite prepared by this method exhibited elongation about 28% that is much more than conventional W-15%wt Cu composites. This method of production for W–Cu composites has not been reported elsewhere

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The present study aims to investigate the role of the electrostatic mechanism in the filtration process of Polyacrylonitrile nanofibers containing single-walled carbon nanotube. The nanofibers were fabricated via electrospinning using 16wt% Polyacrylonitrile polymer (PAN) solution, single-wall carbon nanotubes (SWNT) at a ratio of 99:1 along with N and N-Dimethylformamide solvents. Initial filtration efficiency was tested as per ISO 29463:2011 standard inside a test rig. An electrostatic discharge test was performed via the chemical treatment of the filter media with Isopropyl alcohol in accordance to EN779 standard. Mean initial filtration efficiency of the nanofiber media in the capturing of 100nm and 200nm particles were 95.92% ±2.74 and 97.26% ±1.11 respectively, while for particles between 80nm to 250nm, this was 96.73% ±2.74. The efficiency of the untreated media was 0.2% to 1.2% higher than the PAN/SWNT media after electron discharge using Isopropyl alcohol with an even bigger difference being observed at lower particle size ranges. After treatment with Isopropyl alcohol, the pressure drop of the filtration media was increased from 164.7 Pa to 185.3 Pa. The reduction in filtration efficiency observed after the electrostatic discharge test indicates that the electrical charge of the electrospun nanofibers is influential in its initial efficiency for removing the submicron particles.

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This paper presents the novel fabrication method of a three-dimensional orthogonally woven (3DW) C/C-SiC-ZrB₂ composite and the effects of ZrB₂ and SiC particles on microstructure and the ablation behavior of the C/C–SiC–ZrB₂ composite are studied. C/C–SiC–ZrB₂ composite was prepared by isothermal-chemical vapor infiltration (I-CVI), slurry infiltration (SI), and liquid silicon infiltration (LSI) combined process. Pyrolytic carbon (PyC) was first infused into the 3DW preform by I-CVI at 1050^°C using CH₄ as a precursor in order to form a C/C preform with porous media. The next step was graphitization at 2400^°C for 1hr. Then  ZrB₂ was introduced into 3DW C/C preform with a void percentage of 48 by impregnating the mixture of ZrB₂ and phenolic resin, followed by a pyrolysis step at 1050°C. A liquid Si alloy was infiltrated, at 1650 ^°C, into the 3DW C/C composites porous media containing the ZrB₂ particles to form a SiC–ZrB₂ matrix. An oxyacetylene torch flame was utilized to investigate The ablation behavior. ZrB₂ particles, along with the SiC matrix situated between carbon fiber bundles, form a compact ZrO₂-SiO₂ layer. This layer acts as a barrier, restricting oxygen infiltration into the composite and reducing the erosion of carbon fibers. The findings were supported by FESEM imaging and further confirmed through x-ray diffraction and EDS analysis. The addition of ZrB₂ to the C/C-SiC composite resulted in a lower mass and linear ablation rate; 2.20 mg/s and 1.4 µm/s respectively while those for C/C-SiC composite were 4.8 mg/s and 6.75 µm/s after ablation under an oxyacetylene flame (2500°C) for 120 s.