Showing 6 results for rezvani
M. Rezvani, B. Eftekhari Yekta, V. K. Marghussian,
Volume 5, Issue 1 (winter 2008 2008)
Abstract
Abstract: The application of inexpensive materials such as copper, zinc, lead, iron and steel slag in
manufacturing of glass and glass-ceramic products in construction industry, lining materials as
anti-corrosion and anti-abrasion coatings in metals and etc, has led to considerable progress in
glass technology in recent years. The composition of slag glass-ceramics is mainly located in the
SiO2-Al2O3-CaO-MgO system, in which one of the most important problems is the lack of bulk
crystallization. To resolve the above-mentioned problem, the crystallization behavior of various
compositions containing different nucleating agents Cr2O3 , Fe2O3 and TiO2 in the single, double
and triple forms were studied by differential thermal analysis (DTA).The precipitated crystalline
phases was determined by the X-ray diffractometry and the micro-structural analysis was studies
using the SEM micrographs. The three point bending strength, micro-hardness and the chemical
resistance of the best composition were determined. According to the results, the resulted glassceramic
had a better specification than the stoneware floor tiles and the porcelain one, which are
considered as the two important competitors for it.
A. Rezvanifar, M. Zandrahimi,
Volume 7, Issue 1 (winter 2010 2010)
Abstract
Abstract:
powerful method for the characterization of microstructures of crystalline materials in terms of crystallite size and
dislocation structures. In this paper the effect of the sliding on the microstructure of A356 in the as-cast and heat
treated conditions are studied, The X-ray phase analysis shows that with increasing applied load, the dislocation
density is increased, whereas the crystallite size is decreased. It was found that heat treatment raised dislocation
density during wear. The screw or edge character of dislocations in worn specimens were determined by analyzing the
dislocation contrast factors, it was demonstrated that the character of the prevailing dislocations in high loads is
nearly pure screw.
Diffraction peak profile analysis has recently been developed to such an extent that it can be applied as a
M. Rezvani*,
Volume 7, Issue 4 (Autumn 2010 2010)
Abstract
Abstract: In the present work, effect of the nucleating agent such as TiO2, ZrO2, P2O5, Ye2O3 and CeO2 in single, double, triple and fourth systems on the crystallization behavior of various compositions was studied. Using differential thermal analysis (DTA), the composition of Li2O-Al2O3-SiO2 (LAS) was optimized and the coefficient of thermal expansion (CTE), three point flexural strength, hardness, thermal shock resistance, and chemical resistance of the most favorable composition were evaluated. The crystalline phase was determined by the x-ray diffractometry. Moreover, the micro-structure of the samples was studied by SEM technique. According to the results, -Eucryptites (high quartz solid solution) was the main crystalline phase and the CTE values of the optimized sample were determined as 1.65-1.93 10-6 in the temperature range of 20-500 oC. Furthermore, three point bending strength ranged from 139 to 155 MPa.
M. Rezvani,
Volume 8, Issue 4 (december 2011)
Abstract
The effect of Y2O3, CeO2, P2O5, ZrO2 and TiO2 in single, double and triple form on crystallization mechanism of Li2OAl2O3- SiO2(LAS) glass-ceramic system was investigated .The nucleation and crystallization peak temperatures of optimized samples in each group were determined by Ray & Day method .The crystalline phase was determined by the X-ray diffractometery .The micro-structure of the samples was studied by SEM techniqe .Crystallization activation energy ,E, and kinetic constants(n ,m) were determined by differential thermal analysis (DTA) through Marotta and Augis-Bennet methods .According to the results ,the Avrami constants(m ,n) derived from the Marotta and Augis- Bennett, glasses containing both ZrO2 and TiO2 nuclei were showed bulk crystallization .The crystallization mechanism of specimens containing ZrO2, TiO2 and CeO2 in the triple nuclei series represent two-dimensional bulk crystallization .By comparison of Avrami constants and activation energy of crystallization of optimized samples with other results they gave much lower value of E(255.5 kJ/mol) and higher value of n in 4.38.The lattice constants of the main phase( -eucryptite solid solution)in samples were determined according to the XRD results
M. Zandrahimi, A. Rezvanifar,
Volume 9, Issue 1 (march 2012 2012)
Abstract
Abstract: Cold working performed before an aging treatment has a significant effect on size and amount of precipitate produced. This could be caused by the increase in defect density, such as vacancies and dislocations. In this research, the Al-Cu-Si alloy was solution-treated, wear-tested and then artificially aged for a period of 1–5 h. Changes in the amount of precipitate, in the lattice parameter of the matrix, and in the precipitates are measured by X-ray diffraction and then calculated.It was observed that performing a wear test before the aging treatment was done significantly increased the amount of precipitate, while wear rate decreased.
Parisa Rastgoo Oskoui, Mohammad Rezvani, Abbas Kianvash,
Volume 20, Issue 2 (June 2023)
Abstract
Abstract
The effect of different heat-treatment temperatures on the magnetic, crystallization, and structural properties of 20SiO2.50FeO.30CaO (mol%) glass ceramics was studied. The initial glass was synthesized by the sol-gel method at 25℃ with a precursors to solvent ratio of 1/5. After aging the resulted gel for 24 h at room temperature, it was dried in an electric dryer at 110 ℃ . By heat treatment at different temperatures, different phases such as magnetite, maghemite, and hematite were crystallized in the glass. The maximum stability temperature of magnetite and maghemite were 360℃ and 440℃ respectively. By increasing the heat treatment temperature to higher than 440℃ , the oxidation of maghemite to hematite was occureds. The highest magnetization amount (1.9 emu/g) belonged to sample heat treated at 680℃ . By increasing the heat treatment temperature to 840℃ , the magnetization decreased to 0.8 emu/g, due to the oxidation of maghemite. By increasing the heat treatment temperature from 440℃ to 680℃ , crystalline size of maghemite was increased from 40 to 200 nm. By forther increment of temperature to 840℃ , the size of maghemite crystals decreased to 17nm, due to the oxidation of maghemite to hematite.
Abstract
The effect of different heat-treatment temperatures on the magnetic, crystallization, and structural properties of 20SiO2.50FeO.30CaO (mol%) glass ceramics was studied. The initial glass was synthesized by the sol-gel method at 25℃ with a precursors to solvent ratio of 1/5. After aging the resulted gel for 24 h at room temperature, it was dried in an electric dryer at 110 ℃ . By heat treatment at different temperatures, different phases such as magnetite, maghemite, and hematite were crystallized in the glass. The maximum stability temperature of magnetite and maghemite were 360℃ and 440℃ respectively. By increasing the heat treatment temperature to higher than 440℃ , the oxidation of maghemite to hematite was occureds. The highest magnetization amount (1.9 emu/g) belonged to sample heat treated at 680℃ . By increasing the heat treatment temperature to 840℃ , the magnetization decreased to 0.8 emu/g, due to the oxidation of maghemite. By increasing the heat treatment temperature from 440℃ to 680℃ , crystalline size of maghemite was increased from 40 to 200 nm. By forther increment of temperature to 840℃ , the size of maghemite crystals decreased to 17nm, due to the oxidation of maghemite to hematite.
