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Showing 10 results for Mohammed

N. Mohammed, H. F. Dagher,
Volume 17, Issue 3 (September 2020)
Abstract

Thin films of meta-cinnabar mercuric sulfide (β-HgS) nanoparticles (NPs) was prepared by pulsed laser ablation (PLA) utilizing a pellet of cinnabar mercuric sulfide (α-HgS) was immersed in distilled water (DW). Q-switched Nd:YAG laser of 1064 nm wavelengths with repetition rate (1hz) and fluency (1.5 J/cm2) applied for ablation. Structural, morphological and particle sizes of the β-HgS NPs are invastigated by analyzing XRD, AFM, SEM and TEM measurements. Their crystal structure is transformed from hexagonal (wurtzite) of the α-HgS target material to cubic (zinc blende) β-HgS NPs. The optical properties of the β-HgS NPs are measured by UV–visible spectrophotometer. The direct band gap is calculated to be (2.45eV) of small particles (4-6.2nm) moreover, the band gap value of smallest particles (1-4nm) is (3.47eV) according to the optical transmission spectra

R.s Krishna, J. Mishra, A. Adeniji, Sh. Das, S. Mohammed Mustakim,
Volume 17, Issue 4 (December 2020)
Abstract

The field of nanomaterial has greatly advanced in the last decade following a wider range of applications in the fields of electronics, automobiles, construction, and healthcare due to its extraordinary and ever-evolving properties. Synthesis of the nanomaterial plays a crucial role in redefining the current engineering and science field. At the same time, procuring an environment-friendly end product through eco-friendly solutions and sustainable processes is the key to many global problems. Green synthesis of nanomaterials like graphene and its derivatives involves mild reaction conditions and nontoxic precursors because it is simple, cost-effective, relatively reproducible, and often results in more stable materials. This paper primarily focuses on the green synthesis of graphene and its derivatives (graphene oxide & reduced graphene oxide) and geopolymers; a green technology for preparing graphene reinforced geopolymer composites. Various methods used globally for green synthesis of graphene and geopolymer are briefly discussed and this paper tries to integrate these two areas for a green end product. Possible applications of these green composites are also discussed to provide insights on the current growth and developments. 
Najwa Gouitaa, Lamcharfi Taj-Dine, Bouayad Lamfaddal, Abdi Farid, Mohamed Ounacer, Mohammed Sajieddine,
Volume 18, Issue 2 (June 2021)
Abstract

    The structural and dielectric properties of iron and bismuth co-substituted BaTiO3 ceramic with the formula: B0.95Bi0.05Ti1-xFexO3 for x=0.00 to 1.00, synthesis with solid state route, were characterized.     The X-ray diffraction results show a tetragonal phase for x=0.00. While for x=0.40 to 0.80 we observed a coexistence of tree phase tetragonal, hexagonal and pseudo-cubic. And at x=1.00 only the pseudo-cubic phase is present and the other phase disappeared. The Raman results indicate the existence of tetragonal band for x≤0.40, and an appearance of characteristic bands of Fe3+ ions for more than 0.40 of Fe content. The SEM micrographs show an increase in grain size with the increase of Fe content and it reaches a maximum at x=0.40.  And the Mossbauer spectroscopy indicates that our samples is paramagnetic at room temperature and that the Fe is   oxidized under Fe3+ with no existence of Fe2+ and Fe4+ ions. The temperature dependence of dielectric permittivity was investigated in the frequency range from 20 Hz to 2MHz. The results show three dielectric relaxation phase transitions from a rhombohedral ferroelectric to orthorhombic ferroelectric (TR-O) then to a tetragonal ferroelectric phase (at TO-T), and finally to cubic paraelectric at the Curie temperature (TC).  In addition, the temperature of phase transition shifted to the lower temperature with the increase of Fe content for all the phase transitions. And the maximum of dielectric permittivity increases for TR-O while for TT-O and Tm phases transitions, it reaches a maximum at x=0.60 and x=0.80 respectively and then decreases.

Mohammed Ruhul Amin Bhuiyan, Hayati Mamur,
Volume 18, Issue 3 (September 2021)
Abstract

Carbon-based chemical substances persistence can contribute to adverse health impacts on human lives. It is essential to overcome for treatment purposes. The semiconducting metal oxide is Zinc Oxide (ZnO), which has excellent biocompatibility, good chemical stability, selectivity, sensitivity, non-toxicity, and fast electron transfer characteristics. The ZnO nanoparticles are more efficient compared to other metal oxide materials. Thus, the nanoparticles are in the present research situation to receive increasing attention due to their potential performance of the human body to feel comfortable. The nanoparticles become more promising for biomedical applications through the development of anticancer agents to recovery different types of malignant cells in the human body. The ZnO nanoparticles can be the future potential materials for biomedical applications. The purpose of this paper is to review the cost-effective approach to synthesize the ZnO nanoparticles. Moreover, these ideas can develop for synthesized ZnO biomaterial to perform easily up-scaled in biomedical applications.
Anas Al-Reyahi, Salem Yahya Degs, Ayman Issa, Zyad Khattari, Mohammed Abu Al Sayyed,
Volume 18, Issue 4 (December 2021)
Abstract

The structural properties of a natural clay sample (51% kaolinite) were tweaked to suit specific applications. H2SO4 and NaOH (1.0 M) treatment caused structural alterations and a significant release of Al ions compared to Si ions. Chemical treatment caused structural alterations, according to XRD analysis. FTIR analysis also indicated higher density of polar surface groups upon treatment which affected the corresponding dielectric behaviors. Dielectric measurements shown the suitable application of the materials either as dielectrical insulator and this dependent on the applied frequency. Acid treated kaolinite was reported to be a promising dielectric at 10 and 1000 Hz. With appropriate mass attenuation coefficients (μ/ρ) 12.098-12.182 cm2/g and a high half value layer of 10 cm at 10 keV, kaolinite and other treated forms were adequate shielding materials.
Jaouad Zerhouni, Fouzia Rhazi Filali, Mohammed Naciri Bennani, Omar Qabaqous, Aziz Bouymajane, Jamal Houssaini, Safae Allaoui, Faouzia Benhallam,
Volume 18, Issue 4 (December 2021)
Abstract

Our study is to highlight the effect of the acid-base character and the redox potential of two clays, synthetic anionic Layered Double Hydroxides Zn3Al-CO3 (LDH) clay, and natural commercial cationic clay "Ghassoul" on their antioxidant and antibacterial activities. The antibacterial effect was tested on two Gram-positive bacteria: Staphylococcus aureus and Enterococcus faecalis. Then it was tested on a Gram-negative bacterium: Escherichia coli. The determination of the minimum inhibitory concentration of the two materials was carried out using the microplatemicrotitration technique. The antioxidant activities of clays are assessed by the methods 2.2-diphenyl-1-picrylhydrazyl and the reducing power of iron (Fe3+). The redox potential (Eh) was measured and the redox strength (rH2) was evaluated. The results showed that these materials have an antibacterial effect on the three bacteria tested, the measured zero charge point of Ghassoul (pHzpc =8.75) more basic than that of double layer hydroxide (pHzpc =7.5), redox potential of LDH (-27mV) was higher than that of Gh (- 103mV), and the rH2 of Gh (14.04) was higher compared to anionic clay (13.33).
Keywords: LDHs, Ghassoul, Redox Potential, Zero point of Charge, Antibacterial.

Hussein Ali Jan Miran, Zainab Naji Abdullah, Mohammednoor Altarawneh, M Mahbubur Rahman, Auday Tariq Al-Bayati, Ebtisam M-T. Salman,
Volume 20, Issue 1 (March 2023)
Abstract

This contribution evaluates the influence of Cr doping on the ground state properties of SrTiO3 Perovskite using GGA-PBE approximation. Results of the simulated model infer agreement with the previously published literature. The modification of electronic structure and optical properties due to Cr3+ doping levels in SrTiO3 has been investigated. Structural parameters infer that Cr3+ doping alters the electronic structures of SrTiO3 by shifting the conduction band through lower energies for the Sr and Ti sites. Substituting Ti site by Cr3+ results the energy gap in being eliminated revealing a new electrical case of conducting material for the system. Furthermore, it has been noticed that Cr doping either at Sr or Ti positions could effectively develop the SrTiO3 dielectric constant properties. Consequently, Cr3+ is an effective dopant due to enhancing the optical absorption properties, thus opening up new prospects for optoelectronic applications.
Aqeel Mohammed Hamoudi, Karim Choubani, Mohamed Ben Rabha,
Volume 20, Issue 2 (June 2023)
Abstract

In this work, we demonstrate the beneficial effect of introducing a superficial porous silicon layer on the electronic quality of multi-crystalline silicon for photovoltaic cell application. The porous silicon was formed using an acid vapor etching-based method. The porous silicon layer rich in hydrogen and oxygen formed by vapor etching is an excellent passivating agent for the mc-Si surface. Laser beam-induced current (LBIC) analysis of the exponentiation parameter (n) and surface current mapping demonstrates that oxygen and hydrogen-rich porous silicon led to excellent surface passivation with a strong electronic quality improvement of multi-crystalline silicon.  It was found that the generated current of treated silicon by acid vapor etching-based method is 20 times greater as compared to the reference substrate, owing to recombination centers passivation of the grains and grain boundaries (GBs); The actual study revealed an apparent decrease in the recombination velocity of the minority carrier as reflected by 25% decrease in the exponentiation parameter (n) of the LBIC versus X-position measurements. These results make achieved porous silicon a good option for advancing efficient photovoltaic cells. 
 
Ahmed Hafedh Mohammed Mohammed, Khairul Anuar Bin Shariff, Mohamad Hafizi Abu Bakar,
Volume 20, Issue 4 (December 2023)
Abstract

The coated β-tricalcium phosphate (β-TCP) with dicalcium phosphate dihydrate (DCPD) has attracted much attention in the biomaterials field due to the increase in its osteoconductivity. Besides, the porous bioceramic scaffolds with controlled pore sizes are significant in stimulating bone-like cell activity. In this study, the effect of the setting-time process and acidic-calcium phosphate (CaP) concentrations on the fabrication and properties of porous DCPD/ β-TCP scaffolds were studied. Subsequently, the specimens were examined using X-ray diffraction (XRD), scanning electron microscopy (SEM), compression strength and Fourier transforms infrared (FTIR). The study results revealed that the porous DCPD/ β-TCP scaffolds with macro- and micropore sizes were successfully obtained after the 300-600 µm of porous β-TCP granules were exposed to an acidic-CaP solution. Furthermore, the setting-time process and acidic-CaP concentrations increased the DCPD interlocking between granules, and the mechanical strengths of scaffolds increased up to 0.5 MPa. Meanwhile, the porosity levels were changed based on the formation of DCPD crystals. This study was expected to provide novel insights to researchers in the field of bioceramics through its investigation on the creation of porous DCPD/ β-TCP scaffolds.

 
Hella Houda, Guettaf Temam Elhachmi, Hachemi Ben Temam, Saâd Rahmane, Mohammed Althamthami,
Volume 21, Issue 0 (IN PRESS 2024)
Abstract

In this study, we thoroughly examine β-Bi2O3 thin films as potential photocatalysts. We produced these films using an environmentally friendly Sol Gel method that is also cost-effective. Our research focuses on how different precursor concentrations, ranging from 0.1 M to 0.4 M, affect the photocatalytic performance of these films. We conducted a comprehensive set of tests to analyze various aspects of the films, including their structure, morphology, topography, optical properties, wettability, and photocatalytic capabilities. These tests provided us with a well-rounded understanding of the films' characteristics. To assess their photocatalytic efficiency, we used Methylene Blue (MB) as a contaminant and found that the films, particularly those with a 0.1 M concentration, achieved an impressive 99.9% degradation of MB within four hours. The 0.1 M film had a crystalline size of 39.7 nm, an indirect band gap of 2.99 eV, and a contact angle of 51.37°. Our findings suggest that β-Bi2O3 films, especially the 0.1 M variant, have promising potential for treating effluents from complex industrial dye processes. This research marks a significant step in utilizing sustainable materials to address pollution and environmental remediation challenges.

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